Recovery of valuable metals from spent mobile phone printed circuit boards using biochar in indirect bioleaching

Abstract

Improving the bioleaching efficiency of metals from spent mobile phone printed circuit boards (PCBs) in a short time has been of major interest in recent years. In this paper, a novel cheap catalyst (oak wood biochar) was used to improve the copper and nickel bioleaching efficiency from spent mobile phone PCBs. The biochar was derived from oak wood through slow pyrolysis at a low temperature of 500 °C for 1h. The results of RSM optimization indicated that the optimum conditions to maximize copper and nickel recovery were 1.6 g/L biochar and 16 g/L pulp density. The findings indicated that compared to without the presence of biochar, the leach yields of copper and nickel were high. As much as 98% of copper and 82% of nickel were leached by indirect bioleaching under optimum conditions. The better performance in the presence of biochar is due to both galvanic interactions between biochar and solid waste. The biochemical characterization of bioleaching solution suggested that the high concentration of biochar (> 1.6 g/L) led to copper absorption by functional groups on the surface of biochar. Compared to chemical leaching, the bioleaching has better performance. Under optimum conditions, the copper and nickel recovery by indirect bioleaching was 36% and 64% more than that by chemical leaching. Also, it is found that biochar has a positive effect on the chemical leaching process. Therefore, in this paper, the function of biochar was elaborated not only in bio-hydrometallurgy but also in the hydrometallurgy process.

Keywords: Biological sulfuric acid; Copper recovery; Indirect bioleaching; Oak wood biochar; Spent PCBs.