We report a study to improve the ternary oxide Ni3V2O8's electrochemical energy storage capabilities through correct surfactanization during hydrothermal synthesis. In this study, Ni3V2O8nanomaterials were synthesized in three different forms: one with a cationic surfactant (CTAB), one with an anionic surfactant (SLS), and one without any surfactant. FESEM study reveals that all the synthesized Ni3V2O8nanomaterials had a small stone-like morphology. The electrochemical study showed that anionic surfactant-assisted Ni3V2O8(NVSLS) had a maximum of 972 F g-1specific capacitance at 1 A g-1current density, whereas cationic surfactant-assisted Ni3V2O8(NVCTAB) had the lowest specific capacitance of 162 F g-1. The specific capacitance and the capacitance retention of the NVSLS(85% after 4000 cycles) based electrode was much better than that of the NVCTAB(76% after 4000 cycles) based electrode. The improved energy storage properties of the NVSLSelectrode are attributed to its high diffusion coefficient, high surface area, and enriched elemental nickel, as compared to the NVCTABelectrode. All these excellent electrochemical properties of NVSLSelectrode indicates their potential usage in asymmetric supercapacitor application.
Keywords: Ni3V2O8; energy storage; hydrothermal; supercapacitor; surfactant effect.
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