Synthesis and crystal structures of two related Co and Mn complexes: a celebration of collaboration between the universities of Dakar and Southampton

Abstract

We report the synthesis and structures of two transition-metal complexes involving 2-(2-hy-droxy-phen-yl)benzimidazole (2hpbi - a ligand of inter-est for its photoluminescent applications), with cobalt, namely, bis-[μ-2-(1H-1,3-benzo-diazol-2-yl)phenolato]bis-[ethanol(thio-cyanato)-cobalt(II)], [Co₂(C₁₃H₉N₂O)₂(NCS)₂(C₂H₆O)₂], (1), and manganese, namely, bis-[μ-2-(1H-1,3-benzo-diazol-2-yl)phenolato]bis-{[2-(1H-1,3-benzo-diazol-2-yl)phenolato](thio-cyanato)-mang-an-ese(III)} dihydrate, [Mn₂(C₁₃H₉N₂O)₄(NCS)₂]·2H₂O, (2). These structures are two recent examples of a fruitful collaboration between researchers at the Laboratoire de Chimie de Coordination Organique/Organic Coordination Chemistry Laboratory (LCCO), University of Dakar, Senegal and the National Crystallography Service (NCS), School of Chemistry, University Southampton, UK. This productive partnership was forged through meeting at Pan-African Conferences on Crystallography and quickly grew as the plans for the AfCA (African Crystallographic Association) developed. This article therefore also showcases this productive partnership, in celebration of the IUCr's 75 year anniversary and the recent inclusion of AfCA as a Regional Associate of the IUCr.

Keywords: AfCA–IUCr Virtual Collection; Africa–UK collaboration; cobalt complex; crystal structure; manganese complex; structural chemistry.